ENG_393982.XML
Siemens process gas analyzers have been used in the process industry for more than 40 years, and are renowned for their quality, reliability and measuring accuracy. The flexibility provided by the continuous process gas analyzers with respect to enclosure design, explosion protection, corrosion resistance and communications capability means that optimum solutions can be found for all applications.
Nowadays, the communications capability of analyzers is becoming increasingly important. Siemens process gas analyzers are an integral component of Siemens’ "Totally Integrated Automation" concept which is globally unique. This concept permits design of uniform process communication from the operations management level down to the field level. The simple integration of analyzers into the host control systems is the basis for a uniform automation and analysis solution.
Many years of experience in the development and production of analyzers as well as in the planning and installation of analyzer systems distinguishes Siemens as a solution provider - reliable, innovative and with global presence.
G_PA10_XX_00106
Schematic representation of the measuring procedure of extractive site installations
Extractive procedures for process gas analysis
Extractive process gas analyzers are used for continuous determination of the concentrations of one or more gases in a gas mixture. Determination of the concentration of gases in a process is used to control and monitor process flows, and is therefore decisive for the automation and optimization of processes and ensuring product quality. In addition, process gas analyzers are used to check emissions, thus making an important contribution to environmental protection, as well as for ensuring compliance with statutory directives.
With extractive measuring procedures, the sample to be analyzed is extracted from the process line and applied preconditioned to the analyzer via a sample line and a sample preparation system. This system, for example, adjusts the pressure, temperature and flow of the sample preparation, and frees the sample gas of dust and moisture if necessary. This guarantees that the measurement can be carried out under defined conditions. Furthermore, the analyzer is protected from damaging influences.
Various measuring procedures with different physical and electrochemical methods are used depending on the type of components to be measured and the measuring point. Siemens offers a range of measuring procedures for extractive gas analysis in two device families, SIPROCESS GA700 and series 6 / ULTRAMAT 23. Each device family provides peak analytical performances for its class.
SIPROCESS GA700
The SIPROCESS GA700 device family is the latest generation of Siemens gas analyzers, and features a modular design. Up to two modules can be used per basic unit.
Basic unit
The basic unit is available in three versions: As a 19" rack unit with 3 height units, in an enclosure for wall mounting, and as an Ex-d field device. The communications interfaces present in the basic units can be adapted to the respective process environment or the process control system using additional optionally available electronic modules.
Modules
Depending on the measuring task, the SIPROCESS GA700 can be individually adapted to the respective analytical or process requirements by fitting selectable modules.
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Module
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Measuring task
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ULTRAMAT 7
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The ULTRAMAT 7 module is used for highly-selective measurement of infrared-active components such as CO, CO2, NO, CH4 or SO2. In general, the application area covers many areas, e.g. the use in processes. These are used to control production processes and ensure product quality, even in the presence of highly corrosive gases.
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OXYMAT 7
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The OXYMAT 7 module is used to measure oxygen between 0 to 0.5% (smallest measuring range) and 0 to 100% (largest measuring range). It is designed for use as a field device at ambient temperatures up to 60 °C and allows highly exact measurements through application of the paramagnetic alternating pressure principle. Thanks to the modular design, the OXYMAT 7 module can be combined with an additional module.
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CALOMAT 7
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For determining the concentration of hydrogen and inert gases in binary mixtures by measuring the thermal conductivity. The CALOMAT 7 module features a high dynamic measuring range (e.g. 0 ... 0.5% and 0 ... 100% H2, configurable) and a short T90 time.
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Field control unit
The field control unit with Ex-d explosion protection and flameproof enclosure is approved for use in Zone 1 (ATEX / IECEx approval). Together with the OXYMAT 7 analyzer module it can be used for measuring the oxygen content of flammable or non-flammable gases.
Series 6 / ULTRAMAT 23
The classic analyzers from Siemens, series 6 and ULTRAMAT 23, have been proven at our customers all over the globe in many years of use.
ULTRAMAT 6
For highly-selective measurement of infrared-active components such as CO, CO2, NO, SO2, NH3, H2O, CH4 and other hydrocarbons. The ULTRAMAT 6 is a high-end analyzer in 19" format or in a sturdy field enclosure for use in harsh atmospheres. In general, the application area ranges from all types of emission measurements to use in processes. These serve to control production processes and guarantee product quality, even in the presence of highly corrosive gases.
ULTRAMAT 23
The ULTRAMAT 23 is an innovative multi-component gas analyzer for measuring up to three infrared-sensitive gases using the NDIR principle. Use of a UV photometer enables you to measure even smaller concentrations of SO2 and NO2. Measurement of oxygen (O2) is also possible through the use of electrochemical oxygen sensors or measuring cells operating according to the paramagnetic measuring principle ("dumbbell"). The use of an additional electrochemical H2S measuring cell permits use in biogas applications.
ULTRAMAT/OXYMAT 6
For combined measurement of infrared-active components and oxygen in complex applications.
OXYMAT 6
For measurement of oxygen concentration according to the paramagnetic principle in complex applications. The OXYMAT 6 measures oxygen according to the paramagnetic alternating pressure principle. This guarantees absolute linearity and allows parameterization of very small measuring ranges from 0 to 0.5% (detection limit 50 vpm), up to 0 to 100%, and even 99.5 to 100% in one device.
Suitable materials in the gas path even permit the analyzers to be used for measurement of corrosive gas mixtures. The detector unit does not come into contact with the sample gas, and therefore permits use in harsh conditions while simultaneously guaranteeing a long service life.
OXYMAT 61
For measurement of oxygen concentrations according to the paramagnetic principle in standard applications. Ambient air can be used as the reference gas for OXYMAT 61. This is supplied by a pump integrated in the analyzer enclosure.
OXYMAT 64
For measurement of oxygen concentrations in the trace range by means of ZrO2 sensor technology. The OXYMAT 64 can be used to measure very small traces in the oxygen concentration, down to the smallest measuring range of 0 to 10 vpm. This is particularly interesting in systems for air separation. A catalytically inactive ZrO2 sensor or a catalytically active ZrO2 sensor can be selected, depending on the application.
CALOMAT 6
For determining the concentration of hydrogen and inert gases in binary mixtures by measuring the thermal conductivity. The CALOMAT 6 features a high dynamic measuring range (e.g. 0 … 1% and 0 … 100% H2, configurable) and a short T90 time.
CALOMAT 62
The CALOMAT 62 is a thermal conductivity analyzer that has been specially designed for applications with corrosive gases. It is possible to directly measure the concentration of gas components such as Cl2, HCl and NH3, as well as e.g. H2 and N2 in a corrosive atmosphere.
FIDAMAT 6
For measurement of total hydrocarbons according to the flame ionization principle.
The FIDAMAT variants feature a highly varied application area. From monitoring for traces of hydrocarbons in ultra-pure gases - made possible by the high resolution and small differences in response factors - up to measurements of total hydrocarbons in the % range.
The widely adjustable operating temperature for the sample gas path and detector also allows measurement of high-boiling mixtures and of hydrocarbons at water vapor concentrations up to 100%.
SIPROCESS UV600
Gas analyzer based on UV resonance absorption spectrometry for measuring even very low NO, NO2, SO2, and H2S concentrations.
General information
Introducing flammable gases
Introducing frequently or permanently explosive gas mixtures to the gas analyzers mentioned in this section is not permitted.
The introduction of gases with flammable components at concentrations above the lower explosive limit (LEL) should only be carried out with devices fitted with piping. Purging of the enclosure as well as further measures must be carried out depending on the application. You can find more on this in the section "Extractive continuous process gas analytics" under "Ex-versions". When using SIPROCESS UV600, please contact the technical department. An inert gas must be used for purging (see manual for further information).
Cross-sensitivity
Exact measurement results with regard to the technical specifications can only be expected if a sample gas is free to the greatest possible extent of gases exhibiting a cross-sensitivity with the measured gas component. The influences of these interfering components can be reduced using various measures. Please contact our specialists if you have any questions.
General installation guide and operating conditions
- Protected against low temperatures and thermal radiation (see technical specifications)
- Protected against temperature fluctuations
- To achieve the best possible measuring quality, the mounting location should be free from vibrations
- Protection of electronics from corrosive environments (use field devices with purging if necessary)
- Observation of regulations for installation in hazardous areas (see manual)
- Observation of regulations for measurement in the presence of toxic gases, provide purging of enclosure and further safety measures if necessary (see manual)
- The analyzers in the basic version are set to an interference gas influence of water vapor with a dew point of 4 °C (standard cooler temperature for sample preparation).
- When calibrating with zero gas and span gas, these must be connected via the sample gas cooler analogous to the sample gases to allow correct adjustment.
- In special cases (test measurements or long-term adjustments), it is recommendable to connect the calibration gases via a humidifier upstream of the cooler to avoid "drying-out" of the gas cooler and thus changes in the concentration of the water vapor.
- Correction of cross-interference which may be activated is canceled for the duration of a calibration procedure (zero point and sensitivity).
Calibration/adjustment
The series 6 analyzers (ULTRAMAT 6, OXYMAT 6, CALOMAT 6) as well as the SIPROCESS GA700 analyzers (ULTRAMAT 7, OXYMAT 7, CALOMAT 7) should be calibrated with zero and span gas at least every 14 days.
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Calibration of the analyzers
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Standard
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Zero gas N2 (5.0)
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Span gas
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Sample gas with approx. 60 to 90% of measuring range in residual N2 (5.0)
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Note: With OXYMAT 6/61 and OXYMAT 7, the zero gas and the reference gas must be the same.
- Pre-purging of sample gas path via the sample gas inlet with nitrogen (N2, quality 5.0), duration: min. 1 min, one further minute in addition for each 10 m of sample gas line.
- Calibration gases for zero-point calibration (ULTRAMAT 6, OXYMAT 6, CALOMAT 6, ULTRAMAT 7, OXYMAT 7, CALOMAT 7)
Sufficient supply of inert gas via the sample gas inlet (free from measured component and free from gases with a cross-interference on the measured component), usually N2, quality 5.0.
- Gases for calibration of deflection
Connection of calibration gas via the sample gas inlet (approx. 60 to 90% of the measuring range of the measured component with inert gas as the residual gas (e.g. N2, quality 5.0)).
- Gases for calibration of the CALOMAT 62
Since every residual gas (including nitrogen) has a specific thermal conductivity, the gases used for calibrating the zero point and measuring range end values of the CALOMAT 62 must take this into account. When calibrating e.g. H2 in HCl, HCl can be used as the zero gas (or an appropriate substitute in accordance with the data sheet enclosed with the device) and H2 in HCl (or a substitute gas) as the span gas.
You can find details on FIDAMAT 6, OXYMAT 64 and ULTRAMAT 23 (AUTOCAL) in the sections describing the respective device.
Explosion protection
Refer to the separate manuals, references and standards concerning the topic of explosion protection.
